[(Dibenzo[b,d]thiophen-4-yl)tellanyl]methanethiol
نویسندگان
چکیده
In the title compound, C(13)H(10)S(2)Te, the dibenzothio-phene moiety is almost planar, the maximum atomic deviation being 0.055 (5) Å. The two Te-C bonds are nearly perpen-dicular to each other with a C-Te-C bond angle of 93.0 (2)°. An inter-molecular C-H⋯π inter-action is present between the methyl-ene group and thio-phene ring.
منابع مشابه
Crystal structure of racemic [(1R,2S,3R,4S,6S)-2,6-bis(furan-2-yl)-4-hydroxy-4-(thiophen-2-yl)cyclohexane-1,3-diyl]bis(thiophen-2-ylmethanone). Corrigendum
[This corrects the article DOI: 10.1107/S2056989016009452.].
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The title compound C(18)H(16)N(2)S(2), crystallizes with two independent half-mol-ecules in the asymmetric unit, in one of which the thio-phene rings are disordered in a 0.67:0.33 ratio. Each independent mol-ecule lies across a crystallographic centre of symmetry. The dihedral angle between central (half) benzene ring and the thiophene ring is 11.82°.
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In the crystal of the centrosymmetric title compound, C(20)H(20)N(2)S(2), mol-ecules are linked by head-to-tail C-H⋯N hydrogen bonds, resulting in chains extending along the a axis. Three additional C-H⋯π inter-molecular inter-actions give rise to a herringbone packing motif which extends along the c axis. The C-H⋯N inter-actions provide links between the sheets.
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In the title compound, C28H22O5S3, the central cyclo-hexane ring adopts a chair conformation. The atoms of the furan ring attached to the 6-position of the central cyclo-hexane ring are disordered over two sets of sites with occupancies of 0.832 (5) and 0.168 (5). The hy-droxy group is disordered over two positions (at the 4- and 6-positions of the cyclo-hexane ring) in the ratio 0.832 (5):0.16...
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